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Can the solid state structures of the dihalogen adducts R3EX2 (E = P, As; R = alkyl, aryl; X = Br, I) with the molecular spoke geometry be considered good mimics of the gold(I) systems [(R3E)AuX] (E = As, P; R = alkyl, aryl; X = Cl, Br, I)?
Nicholas A. Barnes, Kevin R. Flower, Saad A. Fyyaz, Stephen M. Godfrey, Alan T. McGown, Philip J. Miles, Robin G. Pritchard and John E. Warrena, CrystEngComm, 2010,12(3), 784-794.
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http://dx.doi.org/10.1039/B917245A
