+++1compound

[TBA]

Уважаемые коллеги! Посмотрите, пож-ста, известен ли комплекс (1:2) хлорида палладия (+2) с Diphenylphosphinostyrene (см. представленную структуру).

C=Cc6ccc([P+](c1ccccc1)(c2ccccc2)[Pd](Cl)(Cl)[P+](c3ccccc3)(c4ccccc4)c5ccc(C... JME 2006.05 Wed Sep 21 18:13:12 IRKST 2011 45 50 0 0 0 0 0 0 0 0999 V2000 12.8181 8.2635 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0000 2.6402 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.9548 5.6194 0.0000 Cl 0 0 0 0 0 0 0 0 0 0 0 0 7.7532 5.5252 0.0000 Cl 0 0 0 0 0 0 0 0 0 0 0 0 11.7064 9.1145 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.1441 1.8333 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.0785 11.1300 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.2001 9.5180 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.8472 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.6597 1.7621 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.7857 10.5927 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.1902 10.2790 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.0190 8.1298 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.4929 10.0554 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.1180 0.5874 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.7301 0.8069 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.7864 3.1563 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.3888 1.1747 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.6046 9.2044 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.3451 8.5548 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.1307 7.2789 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.9406 8.8684 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.5807 1.6456 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.8298 2.2011 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.6423 3.9632 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.2447 1.9816 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.3019 9.4281 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.2325 7.1889 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5590 1.6138 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.5417 3.8149 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.0091 8.8908 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.9397 6.6516 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.1658 1.8651 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.8125 4.4023 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.4136 8.5772 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.4149 2.4207 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.7163 8.3535 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.4235 7.8162 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.1007 2.7885 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.3715 3.3759 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.8280 7.5025 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.9566 3.5954 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.5352 6.9652 0.0000 P 0 3 0 0 0 0 0 0 0 0 0 0 6.2274 4.1828 0.0000 P 0 3 0 0 0 0 0 0 0 0 0 0 6.3542 5.5770 0.0000 Pd 0 0 0 0 0 0 0 0 0 0 0 0 1 5 2 0 0 0 0 2 6 2 0 0 0 0 3 45 1 0 0 0 0 4 45 1 0 0 0 0 5 35 1 0 0 0 0 6 36 1 0 0 0 0 7 11 1 0 0 0 0 7 12 2 0 0 0 0 8 13 1 0 0 0 0 8 14 2 0 0 0 0 9 15 1 0 0 0 0 9 16 2 0 0 0 0 10 17 1 0 0 0 0 10 18 2 0 0 0 0 11 19 2 0 0 0 0 12 20 1 0 0 0 0 13 21 2 0 0 0 0 14 22 1 0 0 0 0 15 23 2 0 0 0 0 16 24 1 0 0 0 0 17 25 2 0 0 0 0 18 26 1 0 0 0 0 19 37 1 0 0 0 0 20 37 2 0 0 0 0 21 38 1 0 0 0 0 22 38 2 0 0 0 0 23 39 1 0 0 0 0 24 39 2 0 0 0 0 25 40 1 0 0 0 0 26 40 2 0 0 0 0 27 31 2 0 0 0 0 27 35 1 0 0 0 0 28 32 1 0 0 0 0 28 35 2 0 0 0 0 29 33 2 0 0 0 0 29 36 1 0 0 0 0 30 34 1 0 0 0 0 30 36 2 0 0 0 0 31 41 1 0 0 0 0 32 41 2 0 0 0 0 33 42 1 0 0 0 0 34 42 2 0 0 0 0 37 43 1 0 0 0 0 38 43 1 0 0 0 0 39 44 1 0 0 0 0 40 44 1 0 0 0 0 41 43 1 0 0 0 0 42 44 1 0 0 0 0 43 45 1 0 0 0 0 44 45 1 0 0 0 0 M CHG 1 43 1 M CHG 1 44 1 M END

[Serty]

По Reaxys не найден. Единственный комплекс который для него описан - Au55(Сабж)12Cl6

[TBA]

Serty, спасибо за поиск!