+++Метод получения тиоамида, Спасибо!!!

[waxman]

Доброго времени суток, помогите пожалуйста найти метод получения о-аминобензтиоамида. Заранее благодарен.

[Arkadii_Tarasevych]

Вот такие ссылки на получение даёт Скайфайндер:

1. Copper(I) bromide-mediated synthesis of novel 2-arylthiazole-5-carboxylates from α-diazo-β-keto esters and aromatic thioamides
By Fontrodona, Xavier; Diaz, Santiago; Linden, Anthony; Villalgordo, Jose M.
From Synthesis (2001), (13), 2021-2027. Language: English, Database: CAPLUS


2. Synthesis of substituted 2-(benzoylamino)thiobenzamides and their ring closure to substituted 2-phenylquinazoline-4-thiones
By Hanusek, Jiri; Hejtmankova, Ludmila; Kubicova, Lenka; Sedlak, Milos
From Molecules [online computer file] (2001), 6(4), 323-337. Language: English, Database: CAPLUS

3. Reactions of 2-aminothiobenzamide with isocyanates. A new synthesis of 2,3-dihydroimidazo[1,2-c]quinazolin-5(6H)-one and 3,4-dihydro-2H-pyrimido[1,2-c]quinazolin-6(7H)-one
By Shiau, Chia Yang; Chern, Ji Wang; Tien, Jung Hsiung; Liu, Kang Chien
From Journal of Heterocyclic Chemistry (1989), 26(3), 595-6. Language: English, Database: CAPLUS

4. Synthesis and x-ray crystal structures of 2,3-dihydro-2-mercapto-2,1,3-benzophosphadiazine-4(1H)-thione 2-sulfide derivatives
By Acheson, R. Morrin; Lines, Claire T.; Bryce, Martin R.; Dauter, Zbigniew; Reynolds, Colin D.; Schmidpeter, Alfred
From Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999) (1985), (12), 1913-17. Language: English, Database: CAPLUS

5. Biological properties of 2,1-benzisothiazole compounds. Antimycotic and antistaphylococcal activities of 3-azomethine derivatives
By Bellotti, A.; Coghi, E.; Sgorbati, O.
From Ateneo Parmense, Acta Naturalia (1976), 12(2), 123-34. Language: Italian, Database: CAPLUS

[Arkadii_Tarasevych]

Методы заключаются в змене кислорода на серу такими реагентами как Lawesson's reagent, P2S5; в реакции о-аминобензонитрила с сульфидом аммония и ещё один в расщеплении 2,3-dihydro-2-mercapto-1,3,2-benzodiazaphosphorine-4(1H)-thione 2-sulfide.

[suprachemister]

RX

о-аминобензтиоамид.pdf