+++Синтез 2-х соединений

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Уважаемые коллеги, помогите пожалуйста найти методы синтеза следующих 2-х соединений

1.

CCOC(=O)C(C(=O)OCC)P(=O)(OCC)OCC JME 2006.05 Wed Oct 05 00:51:00 AMST 2011 19 18 0 0 0 0 0 0 0 0999 V2000 8.4000 2.8152 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.3445 0.0000 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0000 0.3903 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.0000 5.2400 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.2000 5.2400 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.2000 0.3903 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 3.2765 1.4987 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 7.0000 2.8152 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.0000 0.3903 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7000 1.6027 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 0.7000 4.0276 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.3000 4.0276 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 6.3000 1.6027 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 2.1000 1.6027 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 2.1000 4.0276 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.9000 4.0276 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.9000 1.6027 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.2000 2.8152 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8000 2.8152 0.0000 P 0 0 0 0 0 0 0 0 0 0 0 0 1 8 1 0 0 0 0 2 9 1 0 0 0 0 3 10 1 0 0 0 0 4 11 1 0 0 0 0 5 16 2 0 0 0 0 6 17 2 0 0 0 0 7 19 2 0 0 0 0 8 12 1 0 0 0 0 9 13 1 0 0 0 0 10 14 1 0 0 0 0 11 15 1 0 0 0 0 12 16 1 0 0 0 0 13 17 1 0 0 0 0 14 19 1 0 0 0 0 15 19 1 0 0 0 0 16 18 1 0 0 0 0 17 18 1 0 0 0 0 18 19 1 0 0 0 0 M END

и

2. Dimethyl 3,4-furandicarboxylate
CAS: 4282-33-1

Заранее благодарю!!

[suprachemister]

RX

fr1.pdf

fr2.pdf

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Спасибо Suprachemister!!