TiOF2/WO2Cl2 - practical applications

[YuraM]

Good afternoon,
the gas phase formation enthalpies for TiOF2, TiOCl2, WO2Cl2, WO3 are tabulated, e.g. in Glushko books, NIST. My question is how these formation enthalpies could be relevant to the industry? Why do people need them? Is there any relation to the space/aviation industry? This is just out of curiosity question. Thank you!