+++ поиск по SF и Reaxys

[AnMark]

Здравствуйте! Помогите найти информацию и методы синтеза следующих соединений:
1) C1(=C(C(=C(C3=C1C2=C(C(=NC(=C2[H])[H])C([H])([H])[H])[N]3[H])[H])Br)[H])[H]
2) C1(=C(C(=C(C3=C1C2=C(C(=NC(=C2[H])[H])[H])[N]3[H])[H])Br)[H])[H]
3)C1(=C(C(=C(C3=C1C2=C(C(=NC(=C2[H])[H])[H])[N]3[H])[H])OC([H])([H])[H])C)[H]
Заранее спасибо!!

[Chem_DM]

1-2
3 - Reaxys could not find any hits in the database. Note: the query has been expanded automatically and a substructure search based on the original query also didn't find any hits.
Search in reactions as "Any role"
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[AnMark]

Спасибо!!!